Suppose v1,,vmv_1,\dots,v_m is linearly independent in VV and wVw \in V. Show that v1,,vm,wv_1,\dots,v_m,w is linearly independent if and only if

wspan(v1,,vm)w \notin \text{span}(v_1,\dots,v_m)

If wspan(v1,,vm)w \in \text{span}(v_1,\dots,v_m) then

w=a1v1++amvmw = a_1v_1+\dots+a_mv_m

Then v1,,vm,wv_1,\dots,v_m,w is linearly dependent because

a1v1++amvmw=0a_1v_1+\dots+a_mv_m - w = 0

Now suppose v1,,vm,wv_1,\dots,v_m,w is linearly independent, clearly wspan(v1,,vn)w \notin \text{span}(v_1,\dots,v_n) since if it was they'd be dependent as seen above.